《Diphenyl cyclopropenone-centered polymers for site-specific CO-releasing and chain dissociation》 was published in Chinese Chemical Letters in 2020. These research results belong to Shao, Chenchen; Duan, Hanyi; Min, Yuqin; Zhang, Xinghong. Reference of 3-Bromopropan-1-ol The article mentions the following:
The synthesis and stimuli-responsiveness of a di-Ph cyclopropenone (DPCP)-centered poly(Me acrylate) (PMA) are presented. DPCP-centered PMA could release carbon monoxide (CO) upon UV light in a switched on-and-off manner. The CO-releasing process can be reported by the variations in photoluminescence spectra. In addition, DPCP moiety covalently embedded in the crosslinked polyurethane could also release CO under UV light. Of special, DPCP-centered PMA in solution was selectively dissociated at the phenol ester bond under the ultrasound, and a force-induced hydrolyzation reaction was revealed by D2O exchanging 1H NMR spectra. The kinetic study reveals that small quantity of water could enhance the chain scission rate. This work provides a DPCP-centered polymer for site-specific CO-releasing and chain dissociation In the part of experimental materials, we found many familiar compounds, such as 3-Bromopropan-1-ol(cas: 627-18-9Reference of 3-Bromopropan-1-ol)
3-Bromopropan-1-ol(cas: 627-18-9) was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. Furthermore, it was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.Reference of 3-Bromopropan-1-ol
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