In 2022,Kishino, Masamichi; Takaoka, Satoko; Shibutani, Yuki; Kusumoto, Shuhei; Nozaki, Kyoko published an article in Dalton Transactions. The title of the article was 《Synthesis and reactivity of PC(sp3)P-pincer iridium complexes bearing a diborylmethyl anion》.Synthetic Route of C13H26B2O4 The author mentioned the following in the article:
Novel PCP-pincer iridium complexes I (L void, L = CO, Cl) bearing a diborylmethyl anion were synthesized. Strong σ-electron-donation to the metal and significant π-backdonation from the metal to boron atoms at the β-position were observed both exptl. and computationally. H/D exchange of the aromatic C-H bond proceeded smoothly and, in addition, the α-methine-hydrogen between boron atoms was found to be replaced with deuterium in benzene-d6 solution possibly through diborylcarbene metal complexes as intermediates. The experimental part of the paper was very detailed, including the reaction process of Bis[(pinacolato)boryl]methane(cas: 78782-17-9Synthetic Route of C13H26B2O4)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Synthetic Route of C13H26B2O4
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