On June 30, 2006, Fekete, Agnes; Hertkorn, Norbert; Frommberger, Moritz; Lahaniatis, Majlinda R.; Kettrup, Antonius; Schmitt-Kopplin, Philippe published an article.SDS of cas: 4719-04-4 The title of the article was Development of a capillary electrophoresis-mass spectrometry method for the determination of formaldehyde releasers as their hydrolysis products and amino alcohols from metal working fluids. And the article contained the following:
Metal working fluids (MWFs) are widely used as lubricants and coolants for different industrial operations. Biocides are ingredients of MWFs to control the microbial growth; derivatives of hexahydrotriazines and oxazolidines are generally used. Because of the lack of appropriate characterization, an existing capillary electrophoretic method for their quantification was improved. During the process of optimization, it became clear that hydrolysis products, derivatives of amino alcs., severely interfere with the separation procedure. Since indirect-UV detection lacked the required selectivity, mass-selective detection was employed. NMR and MS established the absence of amino alcs. in the original products. The aqueous solutions of the biocides stored for extended time remained amino alc.-free, suggesting that these amino alcs. are formed from the biocides during the capillary electrophoretic separation The observation of narrow and sym. peaks indicated hydrolysis, and the polarity of the products implied favorable conditions for capillary electrophoretic separation Methods were optimized for the anal. of the amino alcs., the hydrolytic products of the formaldehyde releasers, using indirect-UV and MS detection. This method was extended to other likely solutes used as alk.-reserve ingredients. The analytes were separated within 9 min with a high precision of migration times (the RSDs were <1.5%). When quantifying from mobility scale, the calibration curves produced linearity with regression coefficients at 0.990-0.999. The detection limit was <1 mg/L in the case of MS detection. The influence of water-based MWF was also studied, and no matrix effect on the migration of the analytes and on the peak areas was observed The experimental process involved the reaction of 2,2',2''-(1,3,5-Triazinane-1,3,5-triyl)triethanol(cas: 4719-04-4).SDS of cas: 4719-04-4
The Article related to metal working fluid biocide hydrolytic product analysis electrophoresis ms, capillary electrophoresis mass spectrometry amino alc metal working fluid, Organic Analytical Chemistry: Determinations and other aspects.SDS of cas: 4719-04-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts