On May 10, 1999, Hii, King Kuok; Thornton-Pett, Mark; Jutand, Anny; Tooze, Robert P. published an article.Application In Synthesis of 2,2′-(tert-Butylazanediyl)diethanol The title of the article was Syntheses and Properties of Palladium Complexes Containing Phosphorus-Nitrogen-Phosphorus Ligands with a Tunable Hemilabile Site. And the article contained the following:
A series of phosphorus-nitrogen-phosphorus (PNP) ligands of the type R-N(CH2CH2PPh2)2 (R = C(:O)(C6H4OMe-p), tBu, Ph, C6H4OMe-p) have been prepared Their coordination chem. to palladium(II) and palladium(0) complexes was examined using a combination of x-ray crystallog., NMR, and electrochem. techniques. The palladium(0) complexes undergo reactions with aryl iodides to give the palladium(II) complexes [Pd(Ar){R-N(CH2CH2PPh2)2}]+I-, where the rate of oxidative addition was dependent on the nature of the aryl group, as well as the substitution on nitrogen. The experimental process involved the reaction of 2,2′-(tert-Butylazanediyl)diethanol(cas: 2160-93-2).Application In Synthesis of 2,2′-(tert-Butylazanediyl)diethanol
The Article related to palladium phosphorus nitrogen ligand preparation oxidative addition aryl iodide, crystal mol structure phosphorus nitrogen ligand palladium complex, Organometallic and Organometalloidal Compounds: Group Viii – Co, Ni, Ru, Rh, Pd, Os, Ir, Pt and other aspects.Application In Synthesis of 2,2′-(tert-Butylazanediyl)diethanol
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