On September 15, 2021, Xiong, Junping; Zhang, Dejin; Yang, Guoqiang; Zhang, Zhibing published an article.Computed Properties of 96-76-4 The title of the article was Alkylation of Phenol and tert-Butyl Alcohol Catalyzed by Deep Eutectic Solvents under Mild Conditions. And the article contained the following:
Tert-Bu phenol is an important intermediate for organic synthesis and the preparation of tert-Bu phenol under mild conditions is of great significance. In our work, five kinds of deep eutectic solvents were synthesized to catalyze the alkylation of phenol and tert-Bu alc. The deep eutectic solvent consisting of choline bisulfate (ChBf) and p-toluene sulfonic acid (p-TsOH) was proved to be a better catalyst. By employing the response surface methodol. to optimize the reaction conditions, we found that 99.5% conversion of tert-Bu alc. was obtained at a reaction temperature of 30°C. The temperature of alkylation reaction was much milder than those in previous reports. The kinetic model for this reaction was established based on the Runge-Kutta-Fehlberg method and the recycle performance for the catalyst was evaluated. Excellent conversion of tert-Bu alc. can be obtained after recycling eight times. This method provides a potential route for the synthesis of tert-Bu phenol under mild conditions in industry. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Computed Properties of 96-76-4
The Article related to phenol tert butanol alkylation catalyst deep eutectic solvents, Industrial Organic Chemicals, Leather, Fats, and Waxes: Manufacture Of Industrial Organic Chemicals and other aspects.Computed Properties of 96-76-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts