On January 31, 2021, Fu, Xiaomin; Ren, Xiaoqian; Shen, Jiecan; Jiang, Yong; Wang, Yuehua; Orooji, Yasin; Xu, Wenlong; Liang, Jinhua published an article.Electric Literature of 111-29-5 The title of the article was Synergistic catalytic hydrogenation of furfural to 1,2-pentanediol and 1,5-pentanediol with LDO derived from CuMgAl hydrotalcite. And the article contained the following:
A series of layer double metal oxides (LDO) from CuMgAl hydrotalcite precursors were prepared by urea decomposition under different calcination temperatures in this work. Various characterizations including x-ray diffraction, SEM, FTIR, XPS, H2-TPR, NH3-TPD and CO2-TPD were carried out to investigate the structural properties of the as-prepared samples. After calcination at certain temperatures, the resulted LDO presents the excellent catalytic property in the selective hydrogenolysis of furfural (FA) to 1,2-pentanediol (1,2-PeD) and 1,5-pentanediol (1,5-PeD). The Cu+/Cu2+ ratio and the acid-base amount from the calcination process play the key role in the catalytic performance towards this reaction. The optimal catalyst (CuMgAlO-S3) with the maximal Cu+/Cu2+ ratio and the acid-base amount exhibits the best catalytic performance towards hydrogenation of furfural to 1,2-pentanediol (selectivity 55.2%.) and 1,5-pentanediol (selectivity 28.5%) with more than 80% of conversion rate, which indicated the selectivity of 1,2- and 1,5-PeDs counted on the synergistic effect of Cu+ and acid-base properties. The experimental process involved the reaction of Pentane-1,5-diol(cas: 111-29-5).Electric Literature of 111-29-5
The Article related to hydrotalcite layered double oxide catalyst furfural hydrogenolysis pentanediol, Industrial Organic Chemicals, Leather, Fats, and Waxes: Manufacture Of Industrial Organic Chemicals and other aspects.Electric Literature of 111-29-5
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