Leader, Gordon R. published an article in 1973, the title of the article was Use of hexafluoroacetone and fluorine nuclear magnetic resonance to characterize active hydrogen compounds.Synthetic Route of 2160-93-2 And the article contains the following content:
(CF3)2CO in EtOAc solution reacts readily with small amounts of organic compounds containing active H groups to form adducts containing the probe group -C(CF3)2OH. The 19F spectra of these solutions show lines which, in their positions and responses to changes in test conditions, are characteristic of the kind of functional group present and, in finer detail, of the compound tested. H bonding abilities of the unusual -C(CF3)2OH probe group enables it to interact with the solvent and all groups in the compound tested which can be involved in H bonding. Chem. shifts are given for (CF3)2CO adducts of 125 alcs. and amines, illustrating many multifunctional and structural types, and interpreted to show how H bonding affects the discriminating powers of this NMR reagent. The experimental process involved the reaction of 2,2′-(tert-Butylazanediyl)diethanol(cas: 2160-93-2).Synthetic Route of 2160-93-2
The Article related to hexafluoroacetone hydrogen bond nmr, organic compound nmr probe, alc hexafluoroacetone nmr probe, amine hexafluoroacetone nmr probe, Spectra by Absorption, Emission, Reflection, or Magnetic Resonance, and Other Optical Properties: Resonance Spectra and other aspects.Synthetic Route of 2160-93-2
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