On August 12, 2022, Liu, Bowen; Wang, Lei; Qin, Yunfei; Xu, Xianxiu; Zhao, Jinbo published an article.Recommanded Product: 2,4-Di-tert-butylphenol The title of the article was Synthesis of Trisubstituted Chromanes by Lewis-Base-Catalyzed Three-Component Electrophilic Thiofunctionalization of Cyclopropene with Phenols via a Formal [3 + 3] Annulation. And the article contained the following:
A Lewis-base-catalyzed three-component electrophilic thiofunctionalization of cyclopropene with phenol is developed to furnish various trisubstituted chromanes in high trans-diastereoselectivity. This metal-free protocol is easy to scale-up, offers a unique 2,2,3-substitution pattern, and delivers chromanes with diversified core substitution patterns. The unprecedented tolerance of strong electron-withdrawing substituents at the phenol renders the protocol indispensable to access the otherwise inaccessible chromane chem. space that is important for medicinal chem. campaigns. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Recommanded Product: 2,4-Di-tert-butylphenol
The Article related to alkyl aryl arylthio chromane preparation diastereoselective triphenylphosphine sulfide antitumor, phenol cyclopropene phenylsulfenyl phthalimide annulation, Heterocyclic Compounds (One Hetero Atom): Benzopyrans (Including Coumarins, Isocoumarins, Chromones, Benzopyrones, Dibenzopyrans, and Other Arenopyrans) and other aspects.Recommanded Product: 2,4-Di-tert-butylphenol
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