On May 1, 2020, Behera, Rakesh R.; Ghosh, Rahul; Panda, Surajit; Khamari, Subrat; Bagh, Bidraha published an article.Name: Pentane-1,5-diol The title of the article was Hydrosilylation of Esters Catalyzed by Bisphosphine Manganese(I) Complex: Selective Transformation of Esters to Alcohols. And the article contained the following:
A tricarbonylruthenium Xantphos complex I was prepared and characterized by X-ray crystallog.; in the presence of I, esters underwent chemoselective hydrosilylation with phenylsilane under neat conditions (followed by workup with base) to yield esters. Aryl, alkyl, and alkenyl mono- and dicarboxylates and lactones underwent chemoselective reduction to alcs. and diols; ketoesters underwent reduction to diols. Poly(1,6-hexanediol adipate) underwent hydrosilylation to 1,6-hexanediol. The experimental process involved the reaction of Pentane-1,5-diol(cas: 111-29-5).Name: Pentane-1,5-diol
The Article related to alc diol preparation, xantphos manganese complex preparation chemoselective hydrosilylation catalyst crystal structure, manganese catalyst chemoselective hydrosilylation ester and other aspects.Name: Pentane-1,5-diol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts