On January 31, 2013, Li, Yalin; Yang, Hai-Jian; Zhou, Tao published an article.Reference of 2-Methyl-2-propylpropane-1,3-diol The title of the article was New CO2-philic propane derivatives: design, synthesis and phase behavior in supercritical carbon dioxide. And the article contained the following:
Three new potent CO2-philic propane derivatives, i.e. 1,3-bis(3-chloropropionyloxy)-2,2-diethylpropane, 1,3-bis(3-chloropropionyloxy)-2-butyl-2-ethylpropane, and 1,3-bis(3-chloropropionyloxy)-2-methyl-2-propylpropane, were designed and synthesized. Their structures were characterized by NMR, FTIR, and elemental anal. Phase behavior of the three compounds was investigated at temperatures ranging from 313 K to 333 K and pressures from 9.1 MPa to 16.1 MPa in supercritical carbon dioxide, the solubility differences were discussed. The exptl. solubility data were calculated and correlated by the two d.-based models: Bartle and Chrastil, and satisfied agreements were obtained. Addnl., the partial molar volumes V2 for each compound were also estimated in the supercritical phase using the theory developed by Kumar and Johnston. The experimental process involved the reaction of 2-Methyl-2-propylpropane-1,3-diol(cas: 78-26-2).Reference of 2-Methyl-2-propylpropane-1,3-diol
The Article related to propanediol chloropropionic acid diester preparation carbon dioxide philic, solubility supercritical carbon dioxide, kumar johnston theory partial molar volume, bartle chrastil model solubility and other aspects.Reference of 2-Methyl-2-propylpropane-1,3-diol
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