On October 31, 2005, Ghadwal, Rajendra Singh; Mehrotra, Ram C.; Singh, Anirudh published an article.Recommanded Product: 78-26-2 The title of the article was Synthesis and Spectroscopic Characterization of Two Different Types of Heterobimetallic Glycolate Complexes of Niobium(V). And the article contained the following:
An entirely new class of heterobimetallic homoleptic glycolate complexes Nb(OGO)3{Ta(OGO)2} [where G = CMe2CH2CH2CMe2 (G1) (3); CMe2CH2 CHMe (G2) (4); CHMeCHMe (G3) (5); CH2CMe2CH2 (G4) (6); CMe2CMe2(G5) (7); CH2CHMeCH2 (G6) (8); CH2CEt2CH2 (G7) (9); CH2CMe(Pr)CH2 (G8) (10)] were prepared by the reactions of Nb(OGO)2(OGOH) [G = G1 (1a); G2 (1b); G3 (1c); G4 (1d); G5 (1e); G6 (1f); G7 (1g); G8 (1h)] with Ta(OGO)2(OPri) (G = G1 (2a); G2 (2b); G3 (2c); G4 (2d); G5 (2e) G6 (2f); G7 (2g); G8 (2h)). In addition to the novel derivatives (2)-(10), the authors’ earlier studies on heterobimetallic glycolate-alkoxide derivatives were extended to derivatives Nb(OGO) [where M = Al n = 3, G = G3 (11); G4 (12); G6 (13) G7 (14); Gs (15); G9 = CH2CH2CH2 (16) and M = Ti (n = 4, G = G4) (17), Zr (n = 4, G = G4) (18)], which are conveniently prepared by the reactions of metalloligands Nb(OGO)2(OGOH) [G = G3 (1c); G4 (1d); G6 (1f); G7 (1g); G8 (1h); G9 (1i)] with different metal alkoxides. All of these new complexes were characterized by elemental analyses, mol. weight determinations, and spectroscopic (IR and 1H, 27Al-NMR) studies. Structural features of the new derivatives were elucidated from mol. weight and spectroscopic data. The experimental process involved the reaction of 2-Methyl-2-propylpropane-1,3-diol(cas: 78-26-2).Recommanded Product: 78-26-2
The Article related to niobium glycolate heterobimetallic complex with without alkoxide preparation, ir spectra niobium glycolate heterobimetallic complex with without alkoxide, nmr spectra niobium glycolate heterobimetallic complex with without alkoxide and other aspects.Recommanded Product: 78-26-2
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