On June 2, 2017, Vara, Brandon A.; Patel, Niki R.; Molander, Gary A. published an article.Related Products of 386704-04-7 The title of the article was O-Benzyl Xanthate Esters under Ni/Photoredox Dual Catalysis: Selective Radical Generation and Csp3-Csp2 Cross-Coupling. And the article contained the following:
Alkyl xanthate esters are perhaps best known for their use in deoxygenation chem. However, their use in cross-coupling chem. has not been productive, which is due, in part, to inadequate xanthate activation strategies. Herein, we report the use of O-benzyl xanthate esters, readily derived from alcs., as radical pronucleophiles in Csp3-Csp2 cross-couplings under Ni/photoredox dual catalysis. Xanthate (C-O) cleavage is found to be reliant on photogenerated (sec-butyl) radical activators to form new carbon-centered radicals primed for nickel-catalyzed cross-couplings. Mechanistic experiments support the fact that the key radical components are formed independently, and relative rates are carefully orchestrated, such that no cross reactivity is observed The experimental process involved the reaction of (6-(Trifluoromethyl)pyridin-3-yl)methanol(cas: 386704-04-7).Related Products of 386704-04-7
The Article related to cross coupling benzyl xanthate ester nickel photoredox dual catalysis, radical generation xanthate cross coupling, alkyl xanthate esters, carbon-centered radicals, cross-coupling, metal-catalyzed reactions, selective radical generation and other aspects.Related Products of 386704-04-7
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts