On April 1, 2022, Liu, Can; Li, Kang; Shang, Rui published an article.Computed Properties of 386704-04-7 The title of the article was Arenethiolate as a Dual Function Catalyst for Photocatalytic Defluoroalkylation and Hydrodefluorination of Trifluoromethyls. And the article contained the following:
An arene thiolate with an appropriate substituent was photoactivated under visible light to function as both a strongly reducing electron-donating redox catalyst and a HAT catalyst to enable catalytic C-F activation of trifluoromethyl substrates for selective hydrodefluorination and coupling with various alkenes in the presence of formate salts. These reactions demonstrated the promising utility of arenethiolates as dual function photocatalysts. The synthetic utility of this method was demonstrated by the broad scope of amenable trifluoromethyl substrates, including trifluoromethylated (hetero)arenes, trifluoroacetates, and trifluoroacetamides, which exhibited high levels of chemoselectivity. The reaction efficacy allowed site-selective late-stage functionalization of multitrifluoromethylated bioactive compounds and pharmaceuticals. The experimental process involved the reaction of (6-(Trifluoromethyl)pyridin-3-yl)methanol(cas: 386704-04-7).Computed Properties of 386704-04-7
The Article related to difluoroarene preparation, trifluoroarene thiol catalyst photochem defluoroalkylation, difluoroamide preparation, trifluoroacetamide thiol catalyst photochem defluoroalkylation, difluoroacetate preparation, trifluoroacetate thiol catalyst photochem defluoroalkylation and other aspects.Computed Properties of 386704-04-7
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