On August 21, 2015, Dong, Yi; Du, Nana; Li, Xueyuan; Zheng, Litao; Liu, Gang published an article.Category: alcohols-buliding-blocks The title of the article was Tandem Chloropalladation/Cyclization and Dearomative Cyclization toward Functionalized Tricyclic Bridged [3.2.1] Skeleton Compounds. And the article contained the following:
In the presence of PdCl2(MeCN)2 and CuCl2, o-alkenylphenylalkynyl carbonyl compounds such as allyloxyphenylpropynamide I underwent aerobic chemoselective dearomative cyclization reactions to yield fused tricyclic dienones such as II (R = MeO, BuO, EtO, PhCH2O, Me). The structure of II (R = PhCH2O) was determined by X-ray crystallog. The experimental process involved the reaction of 2,4,6-Trihydroxy-3-methylbenzaldehyde(cas: 55743-13-0).Category: alcohols-buliding-blocks
The Article related to fused tricyclic dienone chemoselective preparation, palladium copper catalyst aerobic dearomative cyclization alkenylphenylalkynyl carbonyl compound, tandem aerobic chloropalladation dearomative cyclization alkenylphenylalkynyl carbonyl compound, oxatricyclododecanecarboxamide mol crystal structure and other aspects.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts