On February 7, 2022, Bouchey, Caitlin J.; Tolman, William B. published an article.Synthetic Route of 96-76-4 The title of the article was Involvement of a Formally Copper(III) Nitrite Complex in Proton-Coupled Electron Transfer and Nitration of Phenols. And the article contained the following:
A unique high-valent copper-nitrite species, LCuNO2, was accessed via the reversible one-electron oxidation of [M][LCuNO2] (M = NBu4+ or PPN+). The complex LCuNO2 reacts with 2,4,6-trit-butylphenol (TTBP) via a typical proton-coupled electron transfer (PCET) to yield LCuTHF and the 2,4,6-trit-butylphenoxyl radical. The reaction between LCuNO2 and 2,4-di-t-butylphenol (DTBP) was more complicated. It yielded two products: the coupled bisphenol product expected from a hydrogen atom abstraction and 2,4-di-t-butyl-6-nitrophenol, the product of an unusual anaerobic nitration. Various mechanisms for this latter transformation were considered. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Synthetic Route of 96-76-4
The Article related to preparation copper pyridinylamide nitrite complex, crystal structure copper pyridinylamide nitrite complex, epr spectra copper pyridinylamide nitrite complex, raman spectra copper pyridinylamide nitrite complex, cyclic voltammetry copper pyridinylamide nitrite complex, proton coupled electron transfer reaction copper pyridinylamide nitrite complex and other aspects.Synthetic Route of 96-76-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts