The author of 《Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols》 were Sorribes, Ivan; Lemos, Samantha C. S.; Martin, Santiago; Mayoral, Alvaro; Lima, Renata C.; Andres, Juan. And the article was published in Catalysis Science & Technology in 2019. Electric Literature of C6H15NO The author mentioned the following in the article:
Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcs. is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C-N bond cleavage methodol. is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance. The experimental part of the paper was very detailed, including the reaction process of 6-Aminohexan-1-ol(cas: 4048-33-3Electric Literature of C6H15NO)
6-Aminohexan-1-ol(cas: 4048-33-3) can undergo cyclization over copper supported on γ-alumina and magnesia to form hexahydro-1H-azepine. It may be used along with glutaric acid to generate poly(ester amide)s with excellent film- and fiber forming properties.Electric Literature of C6H15NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts