Synthetic Route of C13H26B2O4In 2019 ,《Stereoselective Desymmetrization of gem-Diborylalkanes by “”Trifluorination””》 was published in Chemistry – A European Journal. The article was written by Kumar, Nivesh; Reddy, Reddy Rajasekhar; Masarwa, Ahmad. The article contains the following contents:
An efficient and general method for the chemoselective synthesis of unsym. gem-diborylalkanes is reported. This method is based on a late-stage desymmetrization through nucleophilic “”trifluorination””, providing chiral gem-diborylalkanes bearing a trifluoroborate group. The reaction offers a highly modular and diastereoselective approach towards the synthesis of gem-diborylcyclopropanes. The utility of the gem-diborylalkane building blocks was demonstrated by selective post-functionalization of the trifluoroborate group. These functionalizations include inter- and intra- Pd-catalyzed Suzuki-Miyaura coupling reactions. The results came from multiple reactions, including the reaction of Bis[(pinacolato)boryl]methane(cas: 78782-17-9Synthetic Route of C13H26B2O4)
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds are versatile intermediates and as such are some of the most important classes of reagents in modern organic chemistry. This stems from their ease of preparation combined with their ability to undergo a broad range of chemical transformations.Synthetic Route of C13H26B2O4
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