Stavber, Stojan; Kosir, Iztok; Zupan, Marko published an article in Journal of Organic Chemistry. The title of the article was 《Reactions of Alcohols with Cesium Fluoroxysulfate》.SDS of cas: 63012-03-3 The author mentioned the following in the article:
The reactions of alcs. with cesium fluoroxysulfate (CsSO4F) in MeCN suspension were studied, and the role of the structure of the alc. and the reaction conditions on the course of reaction was determined Secondary benzyl alcs. bearing a nonactivating aromatic ring were selectively oxidized to the corresponding ketones, while the CsSO4F-mediated reaction of phenyl-1-naphthylmethanol resulted in the formation of 1-fluoronaphthalene and benzaldehyde. Cyclic and noncyclic secondary alcs. were readily converted to ketones, as well as 1-hydroxybenzocyclanes to benzocyclanones-1, without any further fluorination or oxidation under the reaction conditions. On the other hand, reactions of primary alcs. with CsSO4F resulted in the formation of acid fluorides derived from further fluorination of aldehydes. Another type of transformation was observed in the case of alcs. bearing a benzyl functional group attached geminal to a hydroxy group, where decarbonylation of reactive intermediates resulting in the formation of benzyl fluoride derivatives became the main process. 2-Phenylethanol was so converted to benzyl fluoride and phenylacetyl fluoride in a 3:1 relative ratio, while 2-phenyl-1-propanol was selectively transformed to 1-phenyl-1-fluoroethane. The presence of the radical inhibitor nitrobenzene in the reaction mixture considerably inhibited conversion of the starting material. The same effect was observed by lowering the solvent polarity. Hammett correlation anal. of the effect of substituents on the reaction rates of oxidation of a set of substituted 1-phenyl-1-ethanols to acetophenones gave the reaction constant ρ+ = -0.32, while anal. of analogous data for the transformations of benzyl alcs. to benzoyl fluorides gave the value of -0.54. A mechanism including radical intermediates was proposed for the transformation of alcs. by CsSO4F. In the part of experimental materials, we found many familiar compounds, such as (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3SDS of cas: 63012-03-3)
(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains.SDS of cas: 63012-03-3 The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts