《Nano-WO3-SO3H as a New Photocatalyst Insight Through Covalently Grafted Bronsted Acid: Highly Efficient Selective Oxidation of Benzyl Alcohols to Aldehydes》 was written by Hosseini, Saber; Amoozadeh, Ali; Akbarzadeh, Yasaman. Electric Literature of C7H7BrOThis research focused ontungsten oxide benzyl alc aldehyde Bronsted acid oxidation. The article conveys some information:
Modification of nano-WO3 with -SO3H groups as a covalently grafted solid acid reduced its band-gap energy from 2.8 to 2.4 eV and made it an ideal nominee for photocatalytic reaction under visible light irradiation This nano-photocatalyst has been successfully used for the selective oxidation of different benzyl alcs. to corresponding aldehydes under blue LED irradiation The reaction became approx. two times faster with excellent yields. It has shown that the nitrobenzene as an available industrial oxidant is applicable for photocatalytic oxidation of benzyl alc.; remarkably high yield and selectivity have been observed The experimental process involved the reaction of (4-Bromophenyl)methanol(cas: 873-75-6Electric Literature of C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Electric Literature of C7H7BrO It is used in the synthesis of amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts