Stavber, Stojan; Planinsek, Zdenka; Kosir, Iztok; Zupan, Marko published their research in Journal of Fluorine Chemistry on December 31 ,1992. The article was titled 《Substituent modulation of mild fluorination of aromatic molecules with cesium fluoroxysulfate》.Formula: C13H11ClO The article contains the following contents:
Functionalization of mono- and disubstituted benzene derivative with CsSO4F has been modulated by substituents on the benzene ring. α-Hydroxyalkylbenzenes, with a deactivated ring, were oxidized to phenones, while fluorodealkylation was achieved in high yield when electron-donating groups were present in a para position. Electron-withdrawing substituents favored chain fluorofunctionalization in alkylbenzenes, while ring fluorination was found exclusively in acylamino-derivatized alkylbenzenes; fluoro-addition products were formed in the case of p-alkoxy-substituted alkylbenzene derivatives In the experiment, the researchers used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Formula: C13H11ClO)
(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Formula: C13H11ClO
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