Lian, Chen; Li, Hai-Lou; Yang, Guo-Yu published the artcile< A μ-AsO4-Bridging Hexadecanuclear Ni-Substituted Polyoxotungstate>, Product Details of C8H10OS, the main research area is crystal structure arsenate bridging hexadecanuclear nickel substituted silicotungstate; nickel substituted silicotungstate preparation electrochem reduction oxidation catalyst.
A novel tetrahedral μ-AsO4-bridging hexadecanuclear nickel-substituted silicotungstate (ST) Na21H10[(AsO4){Ni8(OH)6(H2O)2(CO3)2(A-α-SiW9O34)2}2]·60H2O (1) was made by the reactions of trivacant [A-α-SiW9O34]10- ({SiW9}) units with Ni2+ cations and Na3AsO4·12H2O and characterized by IR spectrometry, elemental anal., TGA, and powder x-ray diffraction (PXRD). 1 Contains [(AsO4){Ni8(OH)6(H2O)2(CO3)2(A-α-SiW9O34)2}2]31-, a novel polyoxoanion built by four trivacant Keggin [A-α-SiW9O34]10- fragments linked through an unprecedented [(AsO4){Ni8(OH)6(H2O)2(CO3)2}2]9+ cluster, where the tetrahedral AsO4 acts as an exclusively μ2-bridging unit to link multiple Ni centers; such a connection mode appears for the 1st time in polyoxometalate chem. Also, the electrochem. and catalytic oxidation properties of 1 were studied.
Inorganic Chemistry published new progress about Aromatic compounds, sulfones Role: SPN (Synthetic Preparation), PREP (Preparation). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Product Details of C8H10OS.
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