Vieira de Castro, Tomas; Yahiaoui, Oussama; Peralta, Ricardo A.; Fallon, Thomas; Lee, Victor; George, Jonathan H. published the artcile< Biomimetic Synthesis Enables the Structure Revision of Littordials E and F and Drychampone B>, Reference of 4396-13-8, the main research area is biomimetic synthesis littordial E F drychampone B; hetero Diels Alder structure revision littordial drychampone.
Structural reassignments for littordial E, littordial F, and drychampone B are proposed on the basis of consideration of their biosynthetic origin. The key step in the proposed biosynthesis of each of these meroterpenoids is an intermol. hetero-Diels-Alder reaction between an o-quinone methide and caryophyllene or humulene. Biomimetic total synthesis of the natural products gave sufficient material to allow their structure revision by NMR studies.
Organic Letters published new progress about Biomimetic synthesis. 4396-13-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H6O5, Reference of 4396-13-8.
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