Nikoorazm, Mohsen; Rezaei, Ziba; Tahmasbi, Bahman published the artcile< Two Schiff-base complexes of copper and zirconium oxide supported on mesoporous MCM-41 as an organic-inorganic hybrid catalysts in the chemo and homoselective oxidation of sulfides and synthesis of tetrazoles>, Product Details of C8H10OS, the main research area is Schiff base metal complex supported mesoporous MCM41 catalyst preparation; tetrazole green preparation; nitrile sodium azide cycloaddition Schiff base metal complex catalyst; sulfoxide green preparation chemoselective homoselective; sulfide oxidation Schiff base metal complex catalyst.
A simple and efficient procedure was reported for the synthesis of tetrazole derivatives I [R = CH2CN, Ph, 4-BrC6H4, etc.], the chemo and homoselective oxidation of sulfides to sulfoxides R1S(O)R2 [R1 = allyl, n-Bu, Ph, etc.; R2 = Me, CH2CH2OH, Bn, etc.] in the presence of two Schiff-base complexes of zirconium oxide and copper anchored on MCM-41 as mesoporous and organometallic catalysts under green conditions. All the products were obtained in excellent yields with high TOF values indicating the high activity of the synthesized catalysts. These catalysts were characterized by XRD, TGA, SEM, EDS, FT-IR, TEM, WDX, BET and AAS techniques and could be recycled for several times without significant loss in catalytic activity. The recovered catalysts were characterized by SEM, FT-IR and AAS anal. which shown an excellent agreement with fresh catalysts.
Journal of Porous Materials published new progress about [3+2] Cycloaddition reaction. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Product Details of C8H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts