Safety of 2,6-PyridinedimethanolIn 2020 ,《Fast and Efficient Nickel(II)-catalyzed Transfer Hydrogenation of Quinolines with Ammonia Borane》 was published in Advanced Synthesis & Catalysis. The article was written by Vermaak, Vincent; Vosloo, Hermanus C. M.; Swarts, Andrew J.. The article contains the following contents:
The first Ni(II)-catalyzed transfer hydrogenation of quinolines using ammonia borane (AB) as hydrogen (H2) source was reported. An in situ generated Ni(II)-bis(pyrazolyl)pyridine pre-catalyst could hydrogenate quinoline and its derivatives in excellent yields of up to 90% at 25°C in 30 min. Spectroscopic studies revealed that a Ni(II)-hydride was responsible for the transfer hydrogenation of quinoline to 1,2,3,4-tetrahydroquinoline via a 1,4-dihydroquinoline intermediate. In the experiment, the researchers used many compounds, for example, 2,6-Pyridinedimethanol(cas: 1195-59-1Safety of 2,6-Pyridinedimethanol)
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. Pyridines, quinolines, and isoquinolines have found a function in almost all aspects of organic chemistry. Pyridine has found use as a solvent, base, ligand, functional group, and molecular scaffold. As structural elements, these moieties are potent electron-deficient groups, metal-directing functionalities, fluorophores, and medicinally important pharmacophores. Safety of 2,6-Pyridinedimethanol
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