Wang, Yue-Lin; Zhang, Zhong; Li, Hai-Lou; Li, Xu-Yan; Yang, Guo-Yu published the artcile< An Oxalate-Functionalized Tetra-ZrIV-Substituted Sandwich-Type Silicotungstate: Hydrothermal Synthesis, Structural Characterization, and Catalytic Oxidation of Thioethers>, Product Details of C8H10OS, the main research area is thioether oxidation zirconium silicotungstate POM catalyst; sulfoxide preparation zirconium silicotungstate POM catalyst; crystal structure zirconium silicotungstate POM preparation.
A previously unknown inorganic-organic hybrid polyoxidometalate constructed from oxalate-functionalized tetra-ZrIV-substituted dimeric silicotungstate, (NH4)3Na5K6[Zr4(μ3-O)2(μ-OH)2(ox)2(SiW10O37)2]·23H2O (1, ox = oxalate) has been synthesized under mild hydrothermal conditions and characterized by FTIR spectroscopy, elemental anal., TGA, single-crystal and powder x-ray diffraction. Compound 1 contains a centrosym. polyoxidoanion structure with two [SiW10O37]10- units sandwiching a [Zr4(μ3-O)2(μ-OH)2(ox)2]6+ cluster. The catalytic performances of 1 involving oxygenation reactions of thioethers by H2O2 were evaluated, showing that 1 is an excellent catalyst for the catalytic oxidation of thioethers to sulfoxides/sulfones.
European Journal of Inorganic Chemistry published new progress about Crystal structure. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Product Details of C8H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts