Fernandes, Rodney A.; Yadav, Sandhya S.; Kumar, Praveen published the artcile< Palladium-catalyzed anti-Markovnikov oxidative acetalization of activated olefins with iron(III) sulphate as the reoxidant>, Application of C4H8O, the main research area is styrene pinacole palladium catalyst regioselective oxidative acetalization green chem; arylmethyl tetramethyl dioxolane preparation; arylallyl ether pinacole palladium catalyst regioselective acetalization green chem; aryloxyethyl tetramethyl dioxolane preparation; arylacrylate pinacole palladium catalyst regioselective oxidative acetalization green chem; phenyl tetramethyl dioxolanyl acetate preparation; arylhomoallyl alc pinacole palladium catalyst regioselective acetalization green chem; aryltetramethyl dioxolanyl propanol preparation.
This paper disclosed the efficient palladium-catalyzed anti-Markovnikov oxidative acetalization of activated terminal olefins with iron(III) sulfate as the reoxidant. This methodol. required mild reaction conditions and shows high regioselectivity toward anti-Markovnikov products and compatibility with a wide range of functional groups. Iron(III) sulfate was the sole reoxidant used in this method. Various olefins like vinylarenes, aryl-allylethers, aryl or benzyl acrylates and homoallylic alcs. all reacted well providing anti-Markovnikov acetals, some of which represent orthogonally functionalized 1,3- and 1,4-dioxygenated compounds
Organic & Biomolecular Chemistry published new progress about Acetalization (regioselective). 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, Application of C4H8O.
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