Dubey, Atul; Sangwan, Rekha; Mandal, Pintu Kumar published the artcile< N-benzoylglycine/thiourea cooperative catalyzed stereoselective O-glycosidation: Activation of O-glycosyl trichloroacetimidate donors>, Recommanded Product: ((3aR,5R,5aS,8aS,8bR)-2,2,7,7-Tetramethyltetrahydro-3aH-bis([1,3]dioxolo)[4,5-b:4′,5′-d]pyran-5-yl)methanol, the main research area is glycoside preparation benzoylglycine thiourea cooperative catalyzed stereoselective glycosidation; benzoylglycine thiourea cooperative catalyzed stereoselective glycosidation trichloroacetimidate donor activation.
A new practical utility for β-stereoselective glycosylation via activation of O-glycosyl trichloroacetimidate donors using N-benzoylglycine/thiourea cooperative catalysis has been demonstrated. This method represents the first instance where amino acid derived N-benzoylglycine is used as a catalyst for O-glycosylation under mild reaction conditions at ambient temperature NMR spectroscopy studies suggest that thiourea cocatalyst exhibit a cooperative behavior that has a strong effect on the reaction rate, yield, and the β-selectivity.
Catalysis Communications published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 4064-06-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H20O6, Recommanded Product: ((3aR,5R,5aS,8aS,8bR)-2,2,7,7-Tetramethyltetrahydro-3aH-bis([1,3]dioxolo)[4,5-b:4′,5′-d]pyran-5-yl)methanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts