Frey, Guido D.’s team published research in Journal of Organometallic Chemistry in 2006 | CAS: 401797-00-0

2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 401797-00-0) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Formula: C14H21BO2

Frey, Guido D.; Rentzsch, Christoph F.; von Preysing, Denise; Scherg, Tobias; Muehlhofer, Michael; Herdtweck, Eberhardt; Herrmann, Wolfgang A. published their research in Journal of Organometallic Chemistry on December 15 ,2006. The article was titled 《N-Heterocyclic carbenes. Part 48. Rhodium and iridium complexes of N-heterocyclic carbenes: Structural investigations and their catalytic properties in the borylation reaction》.Formula: C14H21BO2 The article contains the following contents:

Bridged and unbridged N-heterocyclic carbene (NHC) ligands are metalated with [Ir/Rh(COD)2Cl]2 to give Rh(I/III) and Ir(I) mono- and biscarbene substituted complexes. All complexes were characterized by spectroscopy, and in addition [Ir(COD)(NHC)2][Cl,I] [COD = 1,5-cyclooctadiene, NHC = 1,3-dimethyl- or 1,3-dicyclohexylimidazolin-2-ylidene] (1, 4, resp.), and the bis(carbene) chelate complexes [(η4-1,5-cyclooctadiene)(1,1′-di-n-butyl-3,3′-ethylene-diimidazolin-2,2′-diylidene)iridium(I) bromide] (12) and [(η4-1,5-cyclooctadiene)(1,1′-dimethyl-3,3′-o-xylylene-diimidazolin-2,2′-diylidene)iridium(I) bromide] (14) were characterized by single crystal x-ray anal. The relative σ-donor/π-acceptor qualities of various NHC ligands were examined and classified in monosubstituted NHC-Rh and NHC-Ir dicarbonyl complexes by IR spectroscopy. For the 1st time, bis(carbene)-substituted Ir complexes were used as catalysts in the synthesis of arylboronic acids starting from pinacolborane and arene derivatives2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 401797-00-0Formula: C14H21BO2) was used in this study.

2-(3,4-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 401797-00-0) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Formula: C14H21BO2

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