《Identification of Prime Factors to Maximize the Photocatalytic Hydrogen Evolution of Covalent Organic Frameworks》 was written by Ghosh, Samrat; Nakada, Akinobu; Springer, Maximilian A.; Kawaguchi, Takahiro; Suzuki, Katsuaki; Kaji, Hironori; Baburin, Igor; Kuc, Agnieszka; Heine, Thomas; Suzuki, Hajime; Abe, Ryu; Seki, Shu. Application of 34374-88-4 And the article was included in Journal of the American Chemical Society in 2020. The article conveys some information:
Visible-light-driven hydrogen (H2) production from water is a promising strategy to convert and store solar energy as chem. energy. Covalent organic frameworks (COFs) are front runners among different classes of organic photocatalysts. The photocatalytic activity of COFs depends on numerous factors such as the electronic band gap, crystallinity, surface area, exciton migration, stability of transient species, charge separation and transport, etc. However, it is challenging to fine tune all of these factors simultaneously to enhance the photocatalytic activity. Hence, in this report, an effort has been made to understand the interplay of these factors and identify the key factors for efficient photocatalytic H2 production through a structure-property-activity relationship. Careful mol. engineering allowed us to optimize all of the above plausible factors impacting the overall catalytic activities of a series of isoreticular COFs. The present study determines three prime factors: light absorption, charge carrier generation, and its transport, which influence the photocatalytic H2 production of COFs to a much greater extent than the other factors.2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Application of 34374-88-4) was used in this study.
2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Regarding monomeric phloroglucinols, this group encompasses acryl phloroglucinols, phloroglucinol-terpene adducts, phloroglucinol glycosides, halogenated phloroglucinols, prenylated phloroglucinols, and cyclicroup polyketides.Application of 34374-88-4
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