《Hierarchical Structure with an Unusual Honeycomb Fullerene Scaffold by a Fullerene-Triphenylene Shape Amphiphile》 was written by Zhang, Wei; Cao, Yan; Lai, Ziwei; Yu, Shichen; Yang, Tingbin; Liu, Xilan; Guo, Qing-Yun; Liu, Yuchu; Chen, Wei; Huang, Mingjun; Wang, Jing; Cheng, Stephen Z. D.. Application In Synthesis of 3-Bromopropan-1-ol And the article was included in Macromolecules (Washington, DC, United States) in 2020. The article conveys some information:
Shape amphiphiles are a class of mols., which contain distinct shapes of building blocks with competing interactions. The building blocks in one mol. are forced connected through chem. bonds, resulting in competition and cooperation of interactions and packings, which leads to interesting assembled structures. In this work, we have designed and synthesized sphere-triangle shape amphiphiles composed of C60 and triphenylene (C60-TP). C60-TP exhibits a hexagonal lattice with unit cell parameters of a = b = 1.98 nm, c = 4.52 nm, and γ = 120°. Also, for the first time, we demonstrated a three-dimensional layered structure with novel honeycomb C60 scaffolds. The coordination number of C60 in the hexagonal lattice plane is tuned to be four, instead of six in a traditional hexagonal close packing. This new type of hexagonal nonclose packing formed by the spatial packing effect of TP moiety could provide general implications for tuning symmetry in hierarchical structures. In the part of experimental materials, we found many familiar compounds, such as 3-Bromopropan-1-ol(cas: 627-18-9Application In Synthesis of 3-Bromopropan-1-ol)
3-Bromopropan-1-ol(cas: 627-18-9) was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. Furthermore, it was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.Application In Synthesis of 3-Bromopropan-1-ol
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