《Chromic acid oxidation of benzhydrols – kinetics and mechanism》 was published in Australian Journal of Chemistry in 1977. These research results belong to Ramanujam, V. M. Sadagopa; Venkatasubramanian, N.; Sundaram, S.. SDS of cas: 63012-03-3 The article mentions the following:
The kinetics of the oxidation of Ph2CHOH and several derivatives by chromium(VI) oxide in aqueous AcOH were studied. The rate of oxidation is expressed as: υ = k3[ArAr’CHOH][CrVI][H+]2. The effect of ring substituents on the rate gives a ρ+ value of -0.546 (r = 0.959) pointing to the development of an electron-deficient centre in the transition state. The oxidation of Ph2CDOH proceeds 6.5 times slower than that of its H analog at 55°C. From the Arrhenius plots, activation parameters were evaluated and the isokinetic relationship was analyzed. The results are discussed in terms of a mechanism involving a rate-determining loss of hydride ion from the α-carbon of benzhydroxy chromate ester. In addition to this study using (3-Chlorophenyl)(phenyl)methanol, there are many other studies that have used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3SDS of cas: 63012-03-3) was used in this study.
(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.SDS of cas: 63012-03-3 Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts