Wang, Jiazhe; Lou, Qixin; Rong, Jingjing; Yang, You published the artcile< Gold(I)-promoted α-selective sialylation of glycosyl ortho-hexynylbenzoates for the latent-active synthesis of oligosialic acids>, Synthetic Route of 4064-06-6, the main research area is sialoside capsular polysaccharide meningitidis; oligosialic acid coupling gold catalyst stereoselective sialylation hexynylbenzoate synthesis.
A gold(I)-promoted α-selective sialylation approach with 5-N,4-O-oxazolidinone-protected sialyl ortho-hexynylbenzoates as donors is described for the stereoselective synthesis of α-sialosides. Iterative couplings of the ‘active’ sialyl ortho-hexynylbenzoates and the ‘latent’ sialyl ortho-iodobenzoates provide a new approach for the ‘latent-active’ synthesis of α-(2→9)-linked oligosialic acids that are relevant to N. meningitidis sero-group C capsular polysaccharide.
Organic & Biomolecular Chemistry published new progress about Coupling reaction. 4064-06-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H20O6, Synthetic Route of 4064-06-6.
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