Han, Xiaoxu; An, Hualiang; Zhao, Xinqiang; Wang, Yanji published the artcile< Influence of acid-base properties on the catalytic performance of Ni/hydroxyapatite in n-butanol Guerbet condensation>, Category: alcohols-buliding-blocks, the main research area is acid base catalytic nickel hydroxyapatite butanol Guerbet condensation.
A series of supported Ni-based multifunctional catalysts were prepared and their catalytic performances for n-butanol Guerbet condensation reaction were evaluated. Ni/hydroxyapatite (HAP) shows the best catalytic performance: a selectivity of 2-ethylhexanol reaches 52.4% at an n-butanol conversion of 29.6% at 230°C. The activity evaluation results indicate that Ni/HAP with both high-d. of acid sites and high-d. of base sites have higher catalytic performance. Furthermore, the importance of acid-base synergistic catalysis was proved by evaluating the change of the catalytic performance of Ni/HAP catalyst after poisoning the acidic or basic sites using an acid or a base probe mol.
Catalysis Communications published new progress about Catalyst poisoning. 104-76-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H18O, Category: alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts