Yi, Xiangli; Hu, Xile published the artcile< Intermolecular oxidative amination of unactivated alkenes by dual photoredox and copper catalysis>, Application In Synthesis of 627-27-0, the main research area is alkene carbomate iridium catalyst photochem regioselective diastereoselective oxidative amination; alkenyl carbamate preparation fluorescence quenching redox potential.
Oxidative amination of alkenes via amidyl radical addition was potentially an efficient method to generate allylic amines, which were versatile synthetic intermediates to bioactive compounds and organic materials. Here by combining photochem. generation of amidyl radicals with Cu-mediated β-H elimination of alkyl radicals, intermol. oxidative amination of unactivated alkenes was developed. The reaction relies on tandem photoredox and copper catalysis and works for both terminal and internal alkenes. The radical nature of the reaction and the mild conditions lead to high functional group tolerance.
Chemical Science published new progress about Alkenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 627-27-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C4H8O, Application In Synthesis of 627-27-0.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts