Armstrong, R. D.; Hirayama, J.; Knight, D. W.; Hutchings, G. J. published the artcile< Quantitative Determination of Pt- Catalyzed D-Glucose Oxidation Products Using 2D NMR>, Safety of D-Glucosaccharic acid, the main research area is platinum catalyzed glucose oxidation 2D NMR.
Quant. correlative 1H-13C NMR has long been discussed as a potential method for quantifying the components of complex reaction mixtures Here, we show that quant. HMBC NMR can be applied to understand the complexity of the catalytic oxidation of glucose to glucaric acid, which is a promising bio-derived precursor to adipic acid, under aqueous aerobic conditions. It is shown through 2D NMR anal. that the product streams of this increasingly studied reaction contain lactone and dilactone derivatives of acid products, including glucaric acid, which are not observable/quantifiable using traditional chromatog. techniques. At 98% glucose conversion, total C6 lactone yield reaches 44%. Furthermore, a study of catalyst stability shows that all Pt catalysts undergo product-mediated chem. leaching. Through catalyst development studies, it is shown that sequestration of leached Pt can be achieved through use of carbon supports.
ACS Catalysis published new progress about Catalyst supports. 87-73-0 belongs to class alcohols-buliding-blocks, and the molecular formula is C6H10O8, Safety of D-Glucosaccharic acid.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts