The author of 《Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions》 were Haubenreisser, Stefan; Woeste, Thorsten H.; Martinez, Claudio; Ishihara, Kazuaki; Muniz, Kilian. And the article was published in Angewandte Chemie, International Edition in 2016. Name: (1S)-1-(2-chlorophenyl)ethane-1,2-diol The author mentioned the following in the article:
Mol. structures of the most prominent chiral non-racemic hypervalent iodine(III) reagents to date have been elucidated for the first time. The formation of a chirally induced supramol. scaffold based on a selective hydrogen-bonding arrangement provides an explanation for the consistently high asym. induction with these reagents. As an exploratory example, their scope as chiral catalysts was extended to the enantioselective dioxygenation of alkenes. A series of terminal styrenes RCH:CH2 (R = Ph, 4-FC6H4, 4-MeO2CC6H4, 3,5-Me2C6H3, 2-naphthyl, etc.) were converted into the corresponding vicinal diacetoxylation products (S)-RCH(OAc)CH2OAc under mild conditions and provided the proof of principle for a truly intermol. asym. alkene oxidation under iodine(I/III) catalysis.(1S)-1-(2-chlorophenyl)ethane-1,2-diol(cas: 133082-13-0Name: (1S)-1-(2-chlorophenyl)ethane-1,2-diol) was used in this study.
(1S)-1-(2-chlorophenyl)ethane-1,2-diol(cas: 133082-13-0) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.Name: (1S)-1-(2-chlorophenyl)ethane-1,2-diol
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