Li, Laiqiang; Hou, Zhong-Wei; Li, Pinhua; Wang, Lei published the artcile< Electrochemical Dearomatizing Spirocyclization of Alkynes with Dimethyl 2-Benzylmalonates to Spiro[4.5]deca-trienones>, Formula: C9H8O, the main research area is alkene dimethyl benzylmalonate ferrocene catalyst electrochem dearomatizing spirocyclization; spiro decatrienone preparation green chem.
An electrochem. dearomatizing spirocyclization of alkynes with di-Me 2-benzylmalonates for the preparation of spiro[4.5]deca-trienones had been developed. This approach adopted ferrocene (Cp2Fe) as an electrocatalyst to produce carbon-centered radical intermediates from C-H-based malonates, which obviated the forthputting of noble-metal reagents, sacrificial chem. oxidants and 2-bromomalonates. A wide variety of spiro compounds were efficiently prepared with satisfactory results under mild conditions.
Journal of Organic Chemistry published new progress about Alkynes, aryl Role: RCT (Reactant), RACT (Reactant or Reagent). 10602-04-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C9H8O, Formula: C9H8O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts