Hofmann, Natalie; Homberg, Leonard; Hultzsch, Kai C. published the artcile< Synthesis of tetrahydroquinolines via borrowing hydrogen methodology using a manganese PN3 pincer catalyst>, Reference of 5344-90-1, the main research area is tetrahydroquinoline preparation.
A straightforward and selective synthesis of 1,2,3,4-tetrahydroquinolines starting from 2-aminobenzyl alcs. and simple secondary alcs. is reported. This one-pot cascade reaction is based on the borrowing hydrogen methodol. promoted by a manganese (I) PN3 pincer complex. The reaction selectively leads to 1,2,3,4-tetrahydroquinolines thanks to a targeted choice of base. This strategy provides an atom-efficient pathway with water as the only byproduct. In addition, no further reducing agents are required.
Organic Letters published new progress about 5344-90-1. 5344-90-1 belongs to class alcohols-buliding-blocks, and the molecular formula is C7H9NO, Reference of 5344-90-1.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts