Larina, Olga V.; Valihura, Karina V.; Kyriienko, Pavlo I.; Vlasenko, Nina V.; Balakin, Dmytro Yu.; Khalakhan, Ivan; Cendak, Tomaz; Soloviev, Sergiy O.; Orlyk, Svitlana M. published the artcile< Successive vapour phase Guerbet condensation of ethanol and 1-butanol over Mg-Al oxide catalysts in a flow reactor>, HPLC of Formula: 104-76-7, the main research area is ethanol butanol Guerbet condensation magnesium aluminum oxide hydrotalcite catalyst.
The successive vapor phase condensation of ethanol and 1-butanol (via Guerbet reaction) in a flow reactor under atm. pressure was studied over catalytic Mg-Al oxide compositions Wherein the vapor phase condensation of 1-butanol to 2-ethyl-1-hexanol in flow has been investigated for the first time. The acid/base capacity ratio, which is determined by the Mg/Al ratio, is an important characteristic for the activity and selectivity of Mg-Al oxide catalysts in the abovementioned processes. The carbon chain length of the reacting alcs., an arrangement of surface active sites and other steric factors also have an impact on Guerbet condensation in the vapor phase. High productivity of Mg-Al oxide system to the Guerbet alcs.: 1-butanol – 25 g/(Lcat·h), 2-ethyl-1-hexanol – 19 g/(Lcat·h), has been achieved. The results have shown a prospect of successive conversion realization: (1) ethanol → 1-butanol; (2) 1-butanol → 2-ethyl-1-hexanol for the production of 2-ethyl-1-hexanol from ethanol.
Applied Catalysis, A: General published new progress about Acidity. 104-76-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H18O, HPLC of Formula: 104-76-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts