Kamatsuka, Takuto; Shinokubo, Hiroshi; Miyake, Yoshihiro published the artcile< Design and synthesis of tunable ligands with 4,4'-bipyridyl as an electron-accepting unit and their rhenium complexes>, Electric Literature of 660867-80-1, the main research area is rhenium bipyridine pendant amine phosphine complex preparation reduction catalyst; carbon dioxide reduction photocatalyst rhenium bipyridine carbonyl complex; crystal structure rhenium bipyridine pendant amine complex; mol structure rhenium bipyridine pendant amine complex.
We have designed and prepared a series of rhenium complexes with 4,4′-bipyridyl, [(2-R1-6-R2-2′-CH2Q-4,4′-bpy)ReCl(CO)3] (2a-i, Q = NEt2, PtBu2, POtBu2; R1, R2 = H, Me, Cl, Br) as an electron-accepting unit. Electrochem. studies revealed that oxidation and reduction of these complexes occurred on the rhenium center and the 4,4′-bipyridyl skeleton, resp. The redox potentials of the rhenium complexes are controllable by tuning the substituents on the 4,4′-bipyridyl skeleton and the coordinating groups to the rhenium center. We have also examined the reactivity of the rhenium complexes in electrochem. and photochem. CO2 reduction
Organometallics published new progress about Crystal structure. 660867-80-1 belongs to class alcohols-buliding-blocks, and the molecular formula is C12H18BNO2, Electric Literature of 660867-80-1.
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