Sequence of hydrogen replacement by lithium or halogen in 2,6-dimethylpyridine was written by Karpman, Ya. S.;Azimov, V. A.;Anisimova, O. S.;Yakhontov, L. N.. And the article was included in Khimiya Geterotsiklicheskikh Soedinenii in 1980.Related Products of 1122-71-0 This article mentions the following:
Reaction of 2,6-lutidine (I) with PhLi in ether with a 1:8 molar ratio of reagent at either room temperature or reflux did not give the dilithio derivatives but gave the monolithio derivatives I did not react with 2.5 mol Br in glacial HOAc at 80-100° without a catalyst or in the presence of ZnCl2 or excess NaOAc. Chlorination of I did not take place at reflux with a 5-fold excess of SO2Cl2. In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0Related Products of 1122-71-0).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Related Products of 1122-71-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts