Iron(III) trifluoroacetate [Fe(O2CCF3)3] catalyzed epoxide opening with amines was written by Erturk, Erkan;Demir, Ayhan S.. And the article was included in ARKIVOC (Gainesville, FL, United States) in 2008.Recommanded Product: Trans-2-(benzylamino)cyclohexanol This article mentions the following:
Non-hygroscopic, non-toxic, and readily available iron(III) trifluoroacetate [Fe(O2CCF3)3] was found to be a highly regioselective catalyst for the ring opening of a wide variety of epoxides with diverse amines under solvent-free conditions. The stereospecific ring opening of (R)-styrene oxide with p-anisidine in the presence of 1 mol% of Fe(O2CCF3)3 gave 2-(p-methoxyphenylamino)-2-phenylethanol (5b) in enantiopure form (>99% ee) within 60 min. In the experiment, the researchers used many compounds, for example, Trans-2-(benzylamino)cyclohexanol (cas: 40571-86-6Recommanded Product: Trans-2-(benzylamino)cyclohexanol).
Trans-2-(benzylamino)cyclohexanol (cas: 40571-86-6) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Recommanded Product: Trans-2-(benzylamino)cyclohexanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts