Synthesis of macrocyclic molecular rods as potential electronic devices was written by Blaszczyk, Alfred;Chadim, Martin;von Haenisch, Carsten;Mayor, Marcel. And the article was included in European Journal of Organic Chemistry in 2006.Application In Synthesis of Sodium 2-methyl-2-propanethiolate This article mentions the following:
The design and synthesis of the macrocycles I (R = H, NO2) as model compounds for the investigation of neg. differential conductance phenomena in mol. junctions are reported. I (R = H, NO2) comprise a mol. rod subunit consisting of three ethynyl-linked Ph rings. While the rotational freedom along the rod axis of both terminal Ph rings is limited by the macrocyclic frame, the central Ph ring is revolving. The rod substructure is terminally functionalized with acetyl-protected thiol groups to enable its immobilization between gold contacts. The central Ph ring is functionalized with one and two nitro groups for I (R = H, NO2). The nitro groups are of particular importance as (i) both macrocycles are model compounds to investigate a hypothetical intramol. interaction of the nitro group with the opposite macrocyclic subunits and (ii) the nitro group(s) result in limited thermal stability of the compounds due to the intramol. rearrangement to macrocycles comprising isatogen subunits. These highly functionalized macrocycles have been assembled by acetylene scaffolding strategies in combination with functional group transformation chem. In the experiment, the researchers used many compounds, for example, Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2Application In Synthesis of Sodium 2-methyl-2-propanethiolate).
Sodium 2-methyl-2-propanethiolate (cas: 29364-29-2) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Application In Synthesis of Sodium 2-methyl-2-propanethiolate
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts