Copper Catalyzed Protosilylation/Protoborylation of gem-Difluoroallenes was written by Shan, Cui-Cui;Dai, Kai-Yang;Zhao, Meng;Xu, Yun-He. And the article was included in European Journal of Organic Chemistry in 2021.Computed Properties of C16H20B2N2O2 This article mentions the following:
We have developed a protocol for protoborylation and protosilylation of gem-difluoroallenes to afford gem-difluoroallyl-boronates and gem-difluoroallylsilanes. It is different from non-fluorine allenes in which nucleophiles are added to 纬-position of gem-difluoroallenes to afford 尾,纬-addition products. Not only monosubstituted gem-difluoroallenes but also disubstituted gem-difluoroallenes could react well with silaboronate (PhMe2Si-Bpin) and bis(pinacolato)diboron (B2pin2). The protocol is simple and efficient to construct compounds which contain tertiary/secondary gem-difluoroallylboronates and gem-difluoroallylsilanes. Moreover, diverse organofluorine compounds can be converted from these organoboronates and silanes. In the experiment, the researchers used many compounds, for example, 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine (cas: 1214264-88-6Computed Properties of C16H20B2N2O2).
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine (cas: 1214264-88-6) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Computed Properties of C16H20B2N2O2
Referemce:
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Alcohols – Chemistry LibreTexts