Photochlorination of organic substances by aqueous chloride ions codissolved with anionic NOx–. Part II. Effect of nitrite was written by Rafanelli, Claudio E.;Petriconi, Gianna L.;Papee, Henry M.. And the article was included in Water, Air, and Soil Pollution in 1978.Name: rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate This article mentions the following:
Aqueous NO2– codissolved with Cl– promotes photochlorination of some reactive organic compounds in contact with those solutions Both overall patterns of the process and the quantum yields of this Cl transfer into the organic phase are very similar to the patterns and yields of reactions which involved NO3– and were carried out under artificial illumination. With analogy to those photoreactions of NO3–-Cl– systems, the overall kinetics outlined in the laboratory for systems comprising NO2– are also followed, with higher quantum yields, under sunlight illumination. In the experiment, the researchers used many compounds, for example, rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6Name: rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate).
rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate (cas: 2451-01-6) belongs to alcohols. The oxygen atom of the strongly polarized O鈥旽 bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Name: rel-(1s,4s)-4-(2-Hydroxypropan-2-yl)-1-methylcyclohexanol hydrate
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts