Hypervalent Iodine(III) Reagents with Transferable Primary Amines: Structure and Reactivity on the Electrophilic 伪-Amination of Stabilized Enolates was written by Poeira, Diogo L.;Negrao, Ana Claudia R.;Faustino, Helio;Coelho, Jaime A. S.;Gomes, Clara S. B.;Gois, Pedro M. P.;Marques, M. Manuel B.. And the article was included in Organic Letters in 2022.SDS of cas: 2216-51-5 This article mentions the following:
A new family of hypervalent iodine reagents containing transferable primary amine groups is described. The benziodoxolone-based reagents were synthesized on a gram-scale through operationally simple reactions in up to quant. yields. These bench-stable solids were characterized by X-ray anal. and successfully employed in the 伪-amination of indanone-based 尾-ketoesters in up to 83% yield. Mechanistic studies indicate a substitution mechanism involving an electrophilic amine. In the experiment, the researchers used many compounds, for example, (1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5SDS of cas: 2216-51-5).
(1R,2S,5R)-2-Isopropyl-5-methylcyclohexanol (cas: 2216-51-5) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.SDS of cas: 2216-51-5
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts