Synthesis of Cu(II) aminoalkoxide complexes and their unusual thermolysis to Cu(0) was written by Park, Jung Woo;Jang, Hong Suk;Kim, Minchan;Sung, Kiwhan;Lee, Sun Sook;Chung, Taek-Mo;Koo, Sangman;Kim, Chang Gyoun;Kim, Yunsoo. And the article was included in Inorganic Chemistry Communications in 2004.Formula: C6H15NO This article mentions the following:
The F free Cu(II) aminoalkoxide complexes Cu(OCMe2CH2NR2)2 (R = Me(I), Et(II)) were synthesized and characterized as a low melting solid (I) and a viscous liquid (II). The complexes are thermally decomposed at <200掳 to produce metallic Cu by unusual 纬-H elimination reaction. In the experiment, the researchers used many compounds, for example, 1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9Formula: C6H15NO).
1-(Dimethylamino)-2-methylpropan-2-ol (cas: 14123-48-9) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Formula: C6H15NO
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts