Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts was written by Liu, Wei-Peng;Yuan, Ming-Lei;Yang, Xiao-Hui;Li, Ke;Xie, Jian-Hua;Zhou, Qi-Lin. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2015.Related Products of 120121-01-9 This article mentions the following:
Highly efficient iridium catalyzed asym. transfer hydrogenation of simple ketones with ethanol as a hydrogen donor has been developed. By using chiral spiro iridium catalysts, a series of alkyl aryl ketones were hydrogenated to chiral alcs. with up to 98% ee. In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9Related Products of 120121-01-9).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Related Products of 120121-01-9
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts