伪-Oxygenation of Benzylic Ethers to Esters Using MnOx-N@C Catalyst was written by Liu, Jing;Wan, Cong;Zheng, Aili;Wang, Lianyue;Yin, Kaiyue;Liu, Dandan;Wang, Shengde;Ren, Lanhui;Gao, Shuang. And the article was included in Youji Huaxue in 2019.Name: (2,4-Dichlorophenyl)methanol This article mentions the following:
A catalytic system for the oxidation of benzylic ethers 2-R-3-R1-4-R2-5-R3-6-R4C6CH2OR5 (R = H, OH, Cl, OMe, etc.; R1 = H, Me, OMe, CF3; RR1 = -CH=CH-CH=CH-; R2 = H, i-Pr, Cl, Ph, etc.; R1R2 = -OCH2O-; R3 = H; R4 = H, Cl; R3R4 = -CH=CH-CH=CH-; R5 = Me, Et, Bn; R4R5 = -(CH2)2-, -CH2-) to esters 2-R-3-R1-4-R2-5-R3-6-R4C6C(O)OR5 has been developed utilizing reusable MnOx-N@C as catalyst and tert-Bu hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up. In the experiment, the researchers used many compounds, for example, (2,4-Dichlorophenyl)methanol (cas: 1777-82-8Name: (2,4-Dichlorophenyl)methanol).
(2,4-Dichlorophenyl)methanol (cas: 1777-82-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Name: (2,4-Dichlorophenyl)methanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts