Some high-potential trithioether chelates of copper was written by Kanters, Rene P. F.;Yu, Ru;Addison, Anthony W.. And the article was included in Inorganica Chimica Acta in 1992.SDS of cas: 1122-71-0 This article mentions the following:
The linear quadridentate ligand 1,8-bis(2′-quinolyl)-3,6-dithiaoctane and the 3 quinquedentate ligands 1,9-bis(2′-pyridyl)-2,5,8-trithianonane, 1,9-bis(6′-methyl-2′-pyridyl)-2,5,8-trithianonane and 1,11-bis(2′-quinolyl)-3,6,9-trithiaundecane were prepared The deep green-blue Cu(II) chelates were characterized by optical and ESR spectroscopy and cyclic voltammetry. The 2 pyridyl chelates had similar tetragonal coordination about the Cu, with an equatorial N2S2 donor set, plus the 3rd thioether S bound axially. The most marked consequence of the pyridine 伪-methylation was that the Cu2+/+ reduction potential was raised by 鈭?00 mV; otherwise, the E1/2 was consonant with previously advanced models for correlating redox potentials with ligand structural features. The pyridyl Cu(II) complexes were isolated as the tetrafluoroborate salts, whereas the quinolyl-Cu(II) chelates were rather redox unstable, in association with even more pos. Cu2+/+聽E1/2 values, similar to that for dibromine reduction In the experiment, the researchers used many compounds, for example, 6-Methyl-2-pyridinemethanol (cas: 1122-71-0SDS of cas: 1122-71-0).
6-Methyl-2-pyridinemethanol (cas: 1122-71-0) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.SDS of cas: 1122-71-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts